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Assistant Professor

Srikanth Nayak

407, CHE Block
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PhD: Iowa State University
Research Interests: Hydrometallurgy, multiphase equilibria and kinetics, interfacial phenomena

Research Overview

Chemical separation processes are fundamental to the chemical industry and consume a large portion of the industrial energy usage. Advances in chemical separations are critical to addressing pressing global and national challenges such as green house gas emissions (separating potent GHG gases from dilute streams), desalination and decontamination, critical mineral extraction and recycling, and nuclear waste processing are some of the prominent examples. Traditional separation processes rely on thermal unit operations such as distillation and evaporation, and are energetically expensive leading to undesirably large ecological and climactic footprint. This has motivated the development of efficient and selective non-thermal separation processes such as ion-exchange and membrane separations. My research is focused on understanding the fundamental drivers of chemical separations and design novel separations media and processes that are scalable, less energy intensive, and environmentally benign. The main focus is on the separation of metallic components from liquid streams. It rests on three pillars: 1) metal complexation in complex electrolytes and confined media, 2) interfacial phenomena in metal separations, and 3) synthesis of selective- and tunable nanomaterials.

Research Highlights

Metal complexation in complex electrolytes

Input streams to separation processes often consist of complex electrolytic solutions that provide rich metal speciation behavior due to the presence of multiple ligands. We study the metal speciation in real and simulated feed streams using analytical and spectroscopic techniques and develop the corresponding thermodynamic models.

Interfacial phenomena in metal separations

Interfacial phenomena are ubiquitous in chemical separations and affect not only separation kinetics, but can also affect the energetics of separations, as they can template the formation of the separated/extracted species and also show metal-ligand complexation behavior that is different from the bulk counterpart. We will study Langmuir monolayers as an effective model to understand the role of interfaces in metal separations.

Synthesis of selective- and tunable nanomaterials for separations

Nanomaterials offer attractive properties with regards to chemical separations such as high surface area that can be functionalized for selective ion capture, tunable morphology, and unique ion solvation and complexation behavior which can be leveraged to enhance chemical separations. We will be synthesizing nanocomposite ion exchange adsorbents and polyelectrolyte membranes designed to selectively capture critical minerals.

Selected Publications

Trivalent Rare Earth Adsorption at Phosphonic Acid Monolayers

Srikanth Nayak and Ahmet Uysal

Journal: ChemPhysChemYear: 2025DOI: https://doi.org/10.1002/cphc.202500429

Spectroscopic Investigation of Cation Effects in U(VI)-NO3- Complexation in Aqueous Solutions

Srikanth Nayak

Journal: RSC AdvancesYear: 2025DOI: https://doi.org/10.1039/D5RA06251A

Speciation and Organic Phase Structure in Nitric Acid Extraction with Trioctylamine

Srikanth Nayak, Michael J Servis, Derrick Combs, Krystian Szeliga, and Soenke Seifert

Journal: Journal of Physical Chemistry BYear: 2024DOI: https://doi.org/10.1021/acs.jpcb.3c08268

Elucidating Trivalent Ion Adsorption at Floating Carboxylic Acid Monolayers: Charge Reversal or Water Reorganization?

Srikanth Nayak, Raju R Kumal, Seung Eun Lee, and Ahmet Uysal

Journal: Journal of Physical Chemistry LettersYear: 2023DOI: https://doi.org/10.1021/acs.jpclett.3c00225

Spontaneous and Ion-Specific Formation of Inverted Bilayers at Air/Aqueous Interface

Srikanth Nayak, Raju R Kumal, and Ahmet Uysal